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Mendeleev Communications, 2020, Volume 30, Issue 3, Pages 293–295
DOI: https://doi.org/10.1016/j.mencom.2020.05.010
(Mi mendc1174)
 

This article is cited in 13 scientific papers (total in 13 papers)

Communications

Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate

D. S. Yambulatova, P. A. Petrovbc, Yu. V. Nelyubinaad, A. A. Starikovae, A. A. Pavlovd, D. Y. Aleshind, S. A. Nikolaevskiia, M. A. Kiskina, M. N. Sokolovbc, I. L. Eremenkoad

a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
c Novosibirsk State University, Novosibirsk, Russian Federation
d A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
e Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
Abstract: An adduct of ZnII pivalate with N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene has been prepared and characterized by X-ray diffraction analysis, NMR spectroscopy and DFT calculations. The compound preserves mononuclear structure in solution and does not switch the coordination mode from normal to abnormal.
Keywords: N-heterocyclic carbenes, carboxylate complexes, zinc(II), DFT calculations, X-ray crystallography.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (947.9 Kb)


Citation: D. S. Yambulatov, P. A. Petrov, Yu. V. Nelyubina, A. A. Starikova, A. A. Pavlov, D. Y. Aleshin, S. A. Nikolaevskii, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate”, Mendeleev Commun., 30:3 (2020), 293–295
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  • https://www.mathnet.ru/eng/mendc/v30/i3/p293
  • This publication is cited in the following 13 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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