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Mendeleev Communications, 2020, Volume 30, Issue 3, Pages 305–307
DOI: https://doi.org/10.1016/j.mencom.2020.05.014
(Mi mendc1178)
 

This article is cited in 6 scientific papers (total in 6 papers)

Communications

Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its AgI, AuI and PtII complexes

M. I. Rogovoya, M. P. Davydovaa, I. Yu. Bagryanskayab, A. V. Artem'eva

a A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
Abstract: A convenient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine has been developed based on reaction of Ph3P with metallic lithium followed by treatment of the Ph2PLi formed with 2-chloropyrazine. The AgI, AuI and PtII chloride complexes derived from this phosphine have been synthesized and structurally characterized.
Keywords: diphenyl(pyrazin-2-yl)phosphine, lithiation, pyrazine, triphenylphosphine, silver(I) complexes, gold(I) complexes, platinum(II) complexes.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (1.6 Mb)


Citation: M. I. Rogovoy, M. P. Davydova, I. Yu. Bagryanskaya, A. V. Artem'ev, “Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its AgI, AuI and PtII complexes”, Mendeleev Commun., 30:3 (2020), 305–307
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  • https://www.mathnet.ru/eng/mendc/v30/i3/p305
  • This publication is cited in the following 6 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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