E. B. Rakhimova, V. Yu. Kirsanov, E. S. Meshcheryakova, A. G. Ibragimov, U. M. Dzhemilev, “Stereochemical outcome of perhydro hexaazadibenzotetracene formation from trans-1,2-diaminocyclohexane”, Mendeleev Commun., 30:3 (2020), 308

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Mendeleev Communications, 2020, Volume 30, Issue 3, Pages 308–310
DOI: https://doi.org/10.1016/j.mencom.2020.05.015 (Mi mendc1179)

This article is cited in 11 scientific papers (total in 11 papers)

Communications

Stereochemical outcome of perhydro hexaazadibenzotetracene formation from trans-1,2-diaminocyclohexane

E. B. Rakhimova, V. Yu. Kirsanov, E. S. Meshcheryakova, A. G. Ibragimov, U. M. Dzhemilev

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Full-text PDF (284 kB) Citations (11) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2020.05.015

Graphic abstract: Stereochemical outcome of perhydro hexaazadibenzotetracene formation from trans-1,2-diaminocyclohexane

Abstract: A one-pot reaction between (±)-trans-1,2-diaminocyclohexane and glyoxal affords intermediate perhydro-1,6,7,12-tetraazatetracene whose further treatment with formaldehyde and (het)arylamines in the presence of YbCl₃·6H₂O gives 2,9-di(het)aryl substituted (3bR*,7aR*,10bR*,14aR*)-perhydro-2,3a,7b,9,10a,14b-hexaazadibenzo[fg,op]tetracenes with cis-junction of the cycles along the C(14c)–C(14d) bond.

Keywords: polyazapolycycles, catalysis, heterocyclization, trans-1,2-diaminocyclohexane, tetraazatetracenes, hexaazadibenzotetracenes.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(2.5 Mb)

Citation: E. B. Rakhimova, V. Yu. Kirsanov, E. S. Meshcheryakova, A. G. Ibragimov, U. M. Dzhemilev, “Stereochemical outcome of perhydro hexaazadibenzotetracene formation from trans-1,2-diaminocyclohexane”, Mendeleev Commun., 30:3 (2020), 308–310

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https://www.mathnet.ru/eng/mendc1179

https://www.mathnet.ru/eng/mendc/v30/i3/p308

This publication is cited in the following 11 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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