E. Yu. Schmidt, N. V. Semenova, E. V. Ivanova, I. A. Ushakov, B. A. Trofimov, “Multimolecular self-organization of acetylene and arylamines into 1-aryl-3-ethyl-4-vinylpyrroles in the KOBut/DMSO system”, Mendeleev Commun., 30:3 (2020), 315

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Mendeleev Communications, 2020, Volume 30, Issue 3, Pages 315–317
DOI: https://doi.org/10.1016/j.mencom.2020.05.018 (Mi mendc1182)

This article is cited in 11 scientific papers (total in 11 papers)

Communications

Multimolecular self-organization of acetylene and arylamines into 1-aryl-3-ethyl-4-vinylpyrroles in the KOBu^t/DMSO system

E. Yu. Schmidt, N. V. Semenova, E. V. Ivanova, I. A. Ushakov, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Full-text PDF (154 kB) Citations (11) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2020.05.018

Graphic abstract: Multimolecular self-organization of acetylene and arylamines into 1-aryl-3-ethyl-4-vinylpyrroles in the KOBu<sup>t</sup>/DMSO system

Abstract: A new superbase-driven self-organization of four molecules of acetylene with one molecule of arylamine to 1-aryl-3ethyl-4-vinylpyrroles in the KOBu^t/DMSO system has been discovered. The process includes four acts of nucleophilic addition to acetylene followed by intramolecular cyclization of intermediate N,N-bis(1,3-dienyl)-N-arylamine.

Keywords: acetylene, arylamines, pyrroles, superbases, nucleophilic addition, self-assemblies.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.0 Mb)

Citation: E. Yu. Schmidt, N. V. Semenova, E. V. Ivanova, I. A. Ushakov, B. A. Trofimov, “Multimolecular self-organization of acetylene and arylamines into 1-aryl-3-ethyl-4-vinylpyrroles in the KOBu^t/DMSO system”, Mendeleev Commun., 30:3 (2020), 315–317

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https://www.mathnet.ru/eng/mendc1182

https://www.mathnet.ru/eng/mendc/v30/i3/p315

This publication is cited in the following 11 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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