V. V. Krivykh, D. A. Panov, F. M. Dolgushin, A. A. Koridze, “Double activation of the diphosphinite pincer proligand by a triosmium carbonyl cluster”, Mendeleev Commun., 30:3 (2020), 374

Mendeleev Communications

RUS ENG

JOURNALS PEOPLE ORGANISATIONS CONFERENCES SEMINARS VIDEO LIBRARY PACKAGE AMSBIB

JavaScript is disabled in your browser. Please switch it on to enable full functionality of the website

	General information
	Latest issue
	Archive

	Search papers
	Search references

	RSS
	Latest issue
	Current issues
	Archive issues
	What is RSS

Mendeleev Commun.:
Year:
Volume:
Issue:
Page:
	Find

Personal entry:
Login:
Password:
	Save password
	Enter
	Forgotten password?
	Register

Mendeleev Communications, 2020, Volume 30, Issue 3, Pages 374–376
DOI: https://doi.org/10.1016/j.mencom.2020.05.038 (Mi mendc1202)

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Double activation of the diphosphinite pincer proligand by a triosmium carbonyl cluster

V. V. Krivykh^a, D. A. Panov^a, F. M. Dolgushin^a, A. A. Koridze^b

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Tbilisi State University, Tbilisi, Georgia

Full-text PDF (305 kB) Citations (1) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2020.05.038

Graphic abstract: Double activation of the diphosphinite pincer proligand by a triosmium carbonyl cluster

Abstract: The reaction between 1,3-bis(diphenylphosphinite)-benzene and Os₃(CO)₁₀(MeCN)₂ affords complex Os₃(CO)₁₀[1,3-(PhPO)₂C₆H₄]. A thermolysis of this cluster in refluxing toluene results in the activation of O–PPh₂ and C–H bonds and the formation of unsaturated triosmium cluster Os₃(μ-H)(μ-PPh₂)(CO)₇[(C₆H₃(O)(OPPh₂)] that possesses a remarkable structure with the pseudo-pincer ligand containing a bridging μ-η¹-aryl group.

Keywords: pincer complexes, pseudo-pincer ligand, osmium cluster, NMR, single crystal X-ray analysis.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(319.8 Kb)

Citation: V. V. Krivykh, D. A. Panov, F. M. Dolgushin, A. A. Koridze, “Double activation of the diphosphinite pincer proligand by a triosmium carbonyl cluster”, Mendeleev Commun., 30:3 (2020), 374–376

Linking options:

https://www.mathnet.ru/eng/mendc1202

https://www.mathnet.ru/eng/mendc/v30/i3/p374

This publication is cited in the following 1 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

Registration to the website

Logotypes