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Mendeleev Communications, 2020, Volume 30, Issue 4, Pages 462–464
DOI: https://doi.org/10.1016/j.mencom.2020.07.018
(Mi mendc1223)
 

This article is cited in 12 scientific papers (total in 12 papers)

Communications

Hydrogenation of acetylene into ethane–ethene mixtures over modified Pd–alumina catalysts

V. I. Bogdanab, A. E. Koklina, A. N. Kalenchukab, L. M. Kustovab

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Abstract: The diffuse-reflectance IR spectroscopic data using acetylene as a probe molecule showed the strengthening of basic properties of γ-Al2O3 modified with alkali metals in the sequence Al2O3 < Na/Al2O3 < K/Al2O3 < Rb/Al2O3 < Cs/Al2O3. The increase in the basicity of the support of Pd–alumina catalysts had a positive effect on the ethene selectivity in hydrogenation of acetylene in an ethane–ethene mixture.
Keywords: acetylene, ethene, hydrogenation, palladium, modification of the support, diffuse reflectance FTIR spectroscopy, DRIFT, acid–base properties.
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Document Type: Article
Language: English


Citation: V. I. Bogdan, A. E. Koklin, A. N. Kalenchuk, L. M. Kustov, “Hydrogenation of acetylene into ethane–ethene mixtures over modified Pd–alumina catalysts”, Mendeleev Commun., 30:4 (2020), 462–464
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  • https://www.mathnet.ru/eng/mendc/v30/i4/p462
  • This publication is cited in the following 12 articles:
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