O. V. Pokidova, B. L. Psikha, A. Yu. Kormukhina, A. I. Kotelnikov, B. S. Fedorov, “Mechanism of the 2-ethyl-3-hydroxy-6-methylpyridinium 2-nitroxysuccinate reduction in nitrite-generating systems”, Mendeleev Commun., 30:4 (2020), 482

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Mendeleev Communications, 2020, Volume 30, Issue 4, Pages 482–484
DOI: https://doi.org/10.1016/j.mencom.2020.07.025 (Mi mendc1230)

This article is cited in 2 scientific papers (total in 2 papers)

Communications

Mechanism of the 2-ethyl-3-hydroxy-6-methylpyridinium 2-nitroxysuccinate reduction in nitrite-generating systems

O. V. Pokidova^a, B. L. Psikha^a, A. Yu. Kormukhina^b, A. I. Kotelnikov^ab, B. S. Fedorov^a

^a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b Department of Fundamental Physical and Chemical Engineering, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

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DOI: https://doi.org/10.1016/j.mencom.2020.07.025

Graphic abstract: Mechanism of the 2-ethyl-3-hydroxy-6-methylpyridinium 2-nitroxysuccinate reduction in nitrite-generating systems

Abstract: The nitrite-generating activity of 2-ethyl-3-hydroxy-6-methylpyridinium 2-nitroxysuccinate as a promising NO-donor has been investigated in reactions with various reducing agents. Reduction of the NO-donor with cysteine was analyzed using a kinetic modeling method. The calculated rate constants satisfactorily describe the experimental data, thereby confirming the proposed reaction mechanism.

Keywords: organic nitrate, thionitrate, cysteine, Griess method, nitrite ion.

Bibliographic databases:

Document Type: Article

Language: English

Citation: O. V. Pokidova, B. L. Psikha, A. Yu. Kormukhina, A. I. Kotelnikov, B. S. Fedorov, “Mechanism of the 2-ethyl-3-hydroxy-6-methylpyridinium 2-nitroxysuccinate reduction in nitrite-generating systems”, Mendeleev Commun., 30:4 (2020), 482–484

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https://www.mathnet.ru/eng/mendc/v30/i4/p482

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