S. A. Rzhevskiy, M. A. Topchiy, Yu. D. Golenko, P. S. Gribanov, G. K. Sterligov, N. Yu. Kirilenko, A. A. Ageshina, M. V. Bermeshev, M. S. Nechaev, A. F. Asachenko, “Undirected ortho-selectivity in C–H borylation of arenes catalyzed by NHC platinum(0) complexes”, Mendeleev Commun., 30:5 (2020), 569

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Mendeleev Communications, 2020, Volume 30, Issue 5, Pages 569–571
DOI: https://doi.org/10.1016/j.mencom.2020.09.005 (Mi mendc1254)

This article is cited in 5 scientific papers (total in 5 papers)

Communications

Undirected ortho-selectivity in C–H borylation of arenes catalyzed by NHC platinum(0) complexes

S. A. Rzhevskiy^a, M. A. Topchiy^a, Yu. D. Golenko^a, P. S. Gribanov^b, G. K. Sterligov^ac, N. Yu. Kirilenko^ac, A. A. Ageshina^a, M. V. Bermeshev^a, M. S. Nechaev^ac, A. F. Asachenko^ab

^a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Full-text PDF (188 kB) Citations (5) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2020.09.005

Graphic abstract: Undirected ortho-selectivity in C–H borylation of arenes catalyzed by NHC platinum(0) complexes

Abstract: Borylation of arenes with bis(pinacolato)diboron catalyzed by sterically encumbered NHC platinum complexes proceeds predominantly at ortho-position even in the absence of a directing group (o : m : p ratio up to 10: 3: 1). The similar borylation with pinacolborane would proceed less selectively.

Keywords: N-heterocyclic carbenes, platinum(0) complexes, borylation, arenes, organoboron compounds, regioselectivity, catalysis.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.6 Mb)

Citation: S. A. Rzhevskiy, M. A. Topchiy, Yu. D. Golenko, P. S. Gribanov, G. K. Sterligov, N. Yu. Kirilenko, A. A. Ageshina, M. V. Bermeshev, M. S. Nechaev, A. F. Asachenko, “Undirected ortho-selectivity in C–H borylation of arenes catalyzed by NHC platinum(0) complexes”, Mendeleev Commun., 30:5 (2020), 569–571

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https://www.mathnet.ru/eng/mendc1254

https://www.mathnet.ru/eng/mendc/v30/i5/p569

This publication is cited in the following 5 articles:

Citing articles in Google Scholar: Russian citations, English citations
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