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Mendeleev Communications, 2020, Volume 30, Issue 5, Pages 589–591
DOI: https://doi.org/10.1016/j.mencom.2020.09.012
(Mi mendc1261)
 

This article is cited in 3 scientific papers (total in 3 papers)

Communications

New 3D metal–organic framework isomer containing trinuclear oxo-centered mixed valence iron

L. Fuab, Q. Yangb, D. Lic, J. Y. Lua

a Department of Chemistry, University of Houston-Clear Lake, Houston, TX, USA
b College of Chemistry and Materials Science, Northwest University, Xi’an, Shaanxi, P.R. China
c College of Materials and Chemical Engineering, China Three Gorges University, Yichang, P.R. China.
Abstract: Reaction of FeCl2·4H2O, 5-bromonicotinic acid and 4,4′-bipyridine under hydrothermal conditions produced a new isomer of [(Feiii)2Feii3-O)(5-bromonicotinato)6]n, which represented 3D metal–organic covalent framework with trinuclear oxo-centered mixed valence iron clusters. Crystal structure of the isomer has been characterized by single crystal X-ray diffraction data and found distinct from the one for the known isomer with 2D structure.
Keywords: coordination polymer, crystal structure, 5-bromonicotinic acid, μ-oxo-centered, trinuclear mixed valence iron.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (635.9 Kb)


Citation: L. Fu, Q. Yang, D. Li, J. Y. Lu, “New 3D metal–organic framework isomer containing trinuclear oxo-centered mixed valence iron”, Mendeleev Commun., 30:5 (2020), 589–591
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  • https://www.mathnet.ru/eng/mendc/v30/i5/p589
  • This publication is cited in the following 3 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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