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Mendeleev Communications, 2020, Volume 30, Issue 6, Pages 760–761
DOI: https://doi.org/10.1016/j.mencom.2020.11.023 (Mi mendc1316) 		 
This article is cited in 6 scientific papers (total in 6 papers)

Communications

The iodine-assisted hydroxyselenenylation of alkenes with elemental selenium

E. O. Kurkutov, T. N. Borodina

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
Full-text PDF (454 kB) Citations (6) Supplementary materials
DOI: https://doi.org/10.1016/j.mencom.2020.11.023
Abstract: β,β′-Dihydroxy selenides are obtained by the iodine-assisted reaction of elemental selenium with alkenes in aqueous acetonitrile in up to 83% yield and ∼1: 1 diastereomeric ratio. The X-ray analysis of bis(2-hydroxycyclohex-1-yl) selenide revealed it to be the trans,trans-isomer indicating that the reaction occurred stereoselectively as anti-addition.
Keywords: iodine-assisted reactions, selenenylation, b-hydroxy selenides, alkenes, organoselenium compounds.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (1.1 Mb)


Citation: E. O. Kurkutov, T. N. Borodina, “The iodine-assisted hydroxyselenenylation of alkenes with elemental selenium”, Mendeleev Commun., 30:6 (2020), 760–761
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  • https://www.mathnet.ru/eng/mendc/v30/i6/p760
    • This publication is cited in the following 6 articles:
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