A. V. Bochanov, S. A. Prikhod’ko, V. V. Bardin, N. Yu. Adonin, “Promising route to aryl(polyfluoroorganyl)borates: aryltris(pentafluorophenyl)borates”, Mendeleev Commun., 35:2 (2025), 128

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Mendeleev Communications, 2025, Volume 35, Issue 2, Pages 128–129
DOI: https://doi.org/10.71267/mencom.7575 (Mi mendc1361)

Communications

Promising route to aryl(polyfluoroorganyl)borates: aryltris(pentafluorophenyl)borates

A. V. Bochanov^ab, S. A. Prikhod’ko^a, V. V. Bardin^c, N. Yu. Adonin^a

^a G .K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
^b Novosibirsk State University, 630090 Novosibirsk, Russian Federation
^c N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

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DOI: https://doi.org/10.71267/mencom.7575

Graphic abstract: Promising route to aryl(polyfluoroorganyl)borates: aryltris(pentafluorophenyl)borates

Abstract: Simple preparation of potassium aryltris(pentafluoro-phenyl)borates by nucleophilic perfluoroarylation of potassium aryltrifluoroborates with C₆F₅MgBr is offered.

Keywords: organofluoroborate anions, polyfluoroarylborates, nucleophilic perfluoroarylation, organofluorine compounds, organoboron compounds.

Funding agency	Grant number
Ministry of Science and Higher Education of the Russian Federation within the governmental assignment for Boreskov lnstitute of Catalysis	FWUR-2024-0035

Received: 22.07.2024
Revised: 20.09.2024

Published: 18.02.2025

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.4 Mb)

Citation: A. V. Bochanov, S. A. Prikhod’ko, V. V. Bardin, N. Yu. Adonin, “Promising route to aryl(polyfluoroorganyl)borates: aryltris(pentafluorophenyl)borates”, Mendeleev Commun., 35:2 (2025), 128–129

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