Abstract:
The reactive phenyl radical, electronically excited benzene monomer and dimer, their radical cations and low-atomic neutral hydrocarbons may be born in situ via the photodissociation/photoionization of a gaseous benzene monomer/dimer photo-desorbed from cosmic ice as well as via the subsequent dissociative recombination of the arisen benzene cations. The above-mentioned species can be the sources for the assembly into large polycyclic aromatic hydrocarbons, which can occur at very low temperatures and pressures in the interstellar medium.
Keywords:
astrochemistry, polycyclic aromatic hydrocarbons, benzene excimer, cosmic photochemistry, interstellar medium, ab initio
calculation.
Citation:
V. A. Terashkevich, E. A. Pazyuk, A. V. Stolyarov, “The feasible photoinduced growth of polycyclic aromatic hydrocarbons from cosmic benzene ice”, Mendeleev Commun., 35:3 (2025), 324–326
Linking options:
https://www.mathnet.ru/eng/mendc1397
https://www.mathnet.ru/eng/mendc/v35/i3/p324
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