E. Yu. Schmidt, N. V. Semenova, I. A. Ushakov, A. V. Vashchenko, B. A. Trofimov, “Diastereoselective synthesis of 5-hydroxy-3-methylalkane-1,6-diones from ketones and acetylene in two atom-economic steps”, Mendeleev Commun., 29:1 (2019), 17

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Mendeleev Communications, 2019, Volume 29, Issue 1, Pages 17–18
DOI: https://doi.org/10.1016/j.mencom.2019.01.004 (Mi mendc1406)

This article is cited in 3 scientific papers (total in 3 papers)

Communications

Diastereoselective synthesis of 5-hydroxy-3-methylalkane-1,6-diones from ketones and acetylene in two atom-economic steps

E. Yu. Schmidt, N. V. Semenova, I. A. Ushakov, A. V. Vashchenko, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Full-text PDF (224 kB) Citations (3) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2019.01.004

Graphic abstract: Diastereoselective synthesis of 5-hydroxy-3-methylalkane-1,6-diones from ketones and acetylene in two atom-economic steps

Abstract: (2R*,4R*)-2-Acetyl-2,6-diaryl-4-methyl-3,4-dihydropyrans (diastereoselectively synthesized from acetylene and ketones in one synthetic operation) undergo ring opening by aqueous NH₄Cl (MeCN, 80°C, 8h) to afford diastereomerically pure 5-hydroxy-1,6-diketones in 48–89% yields.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(197.8 Kb)

Citation: E. Yu. Schmidt, N. V. Semenova, I. A. Ushakov, A. V. Vashchenko, B. A. Trofimov, “Diastereoselective synthesis of 5-hydroxy-3-methylalkane-1,6-diones from ketones and acetylene in two atom-economic steps”, Mendeleev Commun., 29:1 (2019), 17–18

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https://www.mathnet.ru/eng/mendc1406

https://www.mathnet.ru/eng/mendc/v29/i1/p17

This publication is cited in the following 3 articles:

Citing articles in Google Scholar: Russian citations, English citations
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