Abstract:
New monothiolate ruthenium alkylidene complexes bearing bulky tricyclic N-heterocyclic carbene ligands decorated with two geminal trifluoromethyl groups were synthesized. Their catalytic activity in representative olefin metathesis reactions, such as ring closing metathesis of diallyltosylamine and selfmetathesis of allylbenzene, has been evaluated.
Citation:
T. R. Akmalov, S. M. Masoud, D. V. Vorobyeva, F. M. Dolgushin, S. E. Nefedov, S. N. Osipov, “Monothiolate ruthenium alkylidene complexes with tricyclic fluorinated N-heterocyclic carbene ligands”, Mendeleev Commun., 29:1 (2019), 38–40
Linking options:
https://www.mathnet.ru/eng/mendc1413
https://www.mathnet.ru/eng/mendc/v29/i1/p38
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