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Mendeleev Communications, 2019, Volume 29, Issue 1, Pages 55–56
DOI: https://doi.org/10.1016/j.mencom.2019.01.017
(Mi mendc1419)
 

This article is cited in 2 scientific papers (total in 2 papers)

Communications

Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides

O. V. Bityukovab, V. A. Vil'abc, N. V. Lukashinac, A. G. Cherednichenkod, G. I. Nikishina, A. O. Terent'evabc

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b All-Russian Research Institute of Phytopathology, Bol'shiye Vyazemy, Moscow Region, Russian Federation
c D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
d Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
Abstract: Silica gel was found to mediate decarboxylation of tetracarbonyl compounds with a free carboxylic group prepared from β-dicarbonyl compounds and malonyl peroxides. Under solvent-free heterogeneous conditions silica gel effectively acts as a mediator of C–O coupling with further decarboxylation at 120°C.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (3.0 Mb)


Citation: O. V. Bityukov, V. A. Vil', N. V. Lukashin, A. G. Cherednichenko, G. I. Nikishin, A. O. Terent'ev, “Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides”, Mendeleev Commun., 29:1 (2019), 55–56
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  • https://www.mathnet.ru/eng/mendc/v29/i1/p55
  • This publication is cited in the following 2 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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