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Mendeleev Communications, 2024, Volume 34, Issue 3, Pages 409–410
DOI: https://doi.org/10.1016/j.mencom.2024.04.031
(Mi mendc144)
 

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Preparation and crystal structure of D2d-C84(23)Cl24 chlorofullerene

S. I. Troyanov

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Full-text PDF (408 kB) Citations (1)
Abstract: Chlorofullerene D2d-C84(23)Cl24 was prepared by chlorination of D2d-C84(23) with VCl4 or SbCl5 at 320–350 °C. An X-ray crystallographic study with the use of synchrotron radiation revealed the addition pattern of 24 Cl atoms stabilized by the formation of isolated C=C bonds and benzenoid rings on the carbon cage.
Keywords: higher fullerenes, C84, chlorination, IPR isomers, structure elucidation.
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Document Type: Article
Language: English


Citation: S. I. Troyanov, “Preparation and crystal structure of D2d-C84(23)Cl24 chlorofullerene”, Mendeleev Commun., 34:3 (2024), 409–410
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  • https://www.mathnet.ru/eng/mendc/v34/i3/p409
  • This publication is cited in the following 1 articles:
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