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Mendeleev Communications, 2019, Volume 29, Issue 2, Pages 194–195
DOI: https://doi.org/10.1016/j.mencom.2019.03.026
(Mi mendc1468)
 

This article is cited in 3 scientific papers (total in 3 papers)

Communications

New preparative Grignard synthesis of (m-carboranylmethyl)siloxanes from chlorodimethylsiloxanes

B. A. Izmaylov, V. A. Vasnev, G. D. Markova

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Full-text PDF (275 kB) Citations (3)
Abstract: New m-carborane-containing siloxanes were obtained by the Grignard reaction based on chloromethyl-m-carboranes and chlorodimethylsiloxanes. In case of (7-methyl-m-carboran-1-yl)methyl chloride, side processes of isomerization and transmetalation do not occur, which provides the yield of the desired product as high as 87%.
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Document Type: Article
Language: English


Citation: B. A. Izmaylov, V. A. Vasnev, G. D. Markova, “New preparative Grignard synthesis of (m-carboranylmethyl)siloxanes from chlorodimethylsiloxanes”, Mendeleev Commun., 29:2 (2019), 194–195
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  • https://www.mathnet.ru/eng/mendc1468
  • https://www.mathnet.ru/eng/mendc/v29/i2/p194
  • This publication is cited in the following 3 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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