Abstract:
New m-carborane-containing siloxanes were obtained by the Grignard reaction based on chloromethyl-m-carboranes and chlorodimethylsiloxanes. In case of (7-methyl-m-carboran-1-yl)methyl chloride, side processes of isomerization and transmetalation do not occur, which provides the yield of the desired product as high as 87%.
Bibliographic databases:
Document Type:
Article
Language: English
Citation:
B. A. Izmaylov, V. A. Vasnev, G. D. Markova, “New preparative Grignard synthesis of (m-carboranylmethyl)siloxanes from chlorodimethylsiloxanes”, Mendeleev Commun., 29:2 (2019), 194–195
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https://www.mathnet.ru/eng/mendc1468
https://www.mathnet.ru/eng/mendc/v29/i2/p194
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