Abstract:
Novel promising Fe–Pd/γ-Al2O3 catalysts for the selective liquid-phase hydrogenation of unsaturated compounds (phenylacetylene and 2-methylbut-3-yn-2-ol) under ambient conditions have been prepared. They were characterized by low temperature nitrogen adsorption, XRD, SEM, TEM, TPR-H2 and DRIFTS-CO techniques. The presence of Pd–Fe nanoparticles led to increased reactivity and selectivity of the new catalysts in hydrogenation of the C≡C bond to the C=C one as compared to those of the Pd/Al2O3 system.
Citation:
A. A. Shesterkina, L. M. Kozlova, I. V. Mishin, O. P. Tkachenko, G. I. Kapustin, V. P. Zakharov, M. S. Vlaskin, A. Z. Zhuk, O. A. Kirichenko, L. M. Kustov, “Novel Fe–Pd/γ-Al2O3 catalysts for the selective hydrogenation of C≡C bonds under mild conditions”, Mendeleev Commun., 29:3 (2019), 339–342
Linking options:
https://www.mathnet.ru/eng/mendc1517
https://www.mathnet.ru/eng/mendc/v29/i3/p339
This publication is cited in the following 16 articles: