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Mendeleev Communications, 2019, Volume 29, Issue 4, Pages 458–460
DOI: https://doi.org/10.1016/j.mencom.2019.07.035
(Mi mendc1558)
 

This article is cited in 9 scientific papers (total in 9 papers)

Communications

Effect of Buchwald-type ligands on platinum catalyzed hydrosilylation of vinyl terminated polydimethylsiloxane

R. Yu. Lukina, D. A. Emelyanova, A. D. Kachmarzhika, A. V. Sukhova, O. G. Sinyashinb, D. G. Yakhvarovab

a A.M. Butlerov Chemistry Institute, Kazan Federal University, Kazan, Russian Federation
b A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
Abstract: The effect of Buchwald-type ligands on the platinum catalyzed hydrosilylation of vinyl-terminated polydimethylsiloxane has been studied by differential scanning calorimetry of platinum catalyst-containing silicone compositions. Dialkyl(biphenyl-2-yl)phosphines bearing bulky substituents at phosphorus atom are efficient inhibitors of the catalytic hydrosilylation process allowing one to increase the pot-life of silicone composition and to prevent the decomposition of the Pt-based catalyst.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (449.0 Kb)


Citation: R. Yu. Lukin, D. A. Emelyanov, A. D. Kachmarzhik, A. V. Sukhov, O. G. Sinyashin, D. G. Yakhvarov, “Effect of Buchwald-type ligands on platinum catalyzed hydrosilylation of vinyl terminated polydimethylsiloxane”, Mendeleev Commun., 29:4 (2019), 458–460
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  • https://www.mathnet.ru/eng/mendc1558
  • https://www.mathnet.ru/eng/mendc/v29/i4/p458
  • This publication is cited in the following 9 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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