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Mendeleev Communications, 2019, Volume 29, Issue 6, Pages 625–627
DOI: https://doi.org/10.1016/j.mencom.2019.11.006
(Mi mendc1609)
 

This article is cited in 11 scientific papers (total in 11 papers)

Communications

Synthesis and rheological properties of star-shaped polydimethylsiloxanes based on carbosilane dendrimers

P. A. Tikhonova, N. G. Vasilenkoa, G. V. Cherkaeva, V. G. Vasil'evb, N. V. Demchenkoa, E. A. Tatarinovaa, A. M. Muzafarovab

a N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Abstract: The rheological measurements of star-shaped polydimethylsiloxanes with 8, 32 and 128 arms synthesized from carbosilane dendrimers of 2nd, 4th and 6th generations, respectively, revealed the Newtonian character of flow in the systems with 8 or 32 arms and a pseudoplastic character of flow in the 128-arm one. The activation energy of viscous flow was found to be 18.5kJmol−1 for all the objects.
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Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (1.1 Mb)


Citation: P. A. Tikhonov, N. G. Vasilenko, G. V. Cherkaev, V. G. Vasil'ev, N. V. Demchenko, E. A. Tatarinova, A. M. Muzafarov, “Synthesis and rheological properties of star-shaped polydimethylsiloxanes based on carbosilane dendrimers”, Mendeleev Commun., 29:6 (2019), 625–627
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  • https://www.mathnet.ru/eng/mendc/v29/i6/p625
  • This publication is cited in the following 11 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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