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Mendeleev Communications, 2019, Volume 29, Issue 6, Pages 666–668
DOI: https://doi.org/10.1016/j.mencom.2019.11.021
(Mi mendc1624)
 

This article is cited in 7 scientific papers (total in 7 papers)

Communications

Influence of the electronic state of the metals in Fe–Pt/SiO2 catalysts on the performance of hydrogenation of phenylacetylene

A. A. Shesterkinaa, O. P. Tkachenkoa, E. V. Shuvalovaa, G. I. Kapustina, V. B. Kazanskiia, L. M. Kustovab

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Abstract: Iron-modified platinum bimetallic system, 1% Pt–1% Fe/SiO2, provides selective liquid-phase hydrogenation of phenylacetylene into styrene at 70°C and 5 atm. This effect is attributed to the electron enrichment of the Pt surface atoms due to a charge transfer from Fe to Pt or contact interactions between these two metals, as indicated by XPS and DRIFTS-CO.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (605.3 Kb)


Citation: A. A. Shesterkina, O. P. Tkachenko, E. V. Shuvalova, G. I. Kapustin, V. B. Kazanskii, L. M. Kustov, “Influence of the electronic state of the metals in Fe–Pt/SiO2 catalysts on the performance of hydrogenation of phenylacetylene”, Mendeleev Commun., 29:6 (2019), 666–668
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  • https://www.mathnet.ru/eng/mendc/v29/i6/p666
  • This publication is cited in the following 7 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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