Abstract:
The polybromide complex (Et4N)3{[Bi2Br9](Br2)} was obtained by reaction of [BiBr6]3–, Br2 and tetraethylammonium bromide in 2 m HBr. In its crystal structure, bioctahedral [Bi2Br9]3– anions are connected by neutral Br2 linkers into infinite 1D chains via terminal bromide ligands.
Citation:
S. A. Adonin, I. D. Gorokh, P. A. Abramov, I. V. Korolkov, M. N. Sokolov, V. P. Fedin, “A novel polybromide complex of bismuth – (Et4N)3{[Bi2Br9](Br2)}: synthesis and structural features”, Mendeleev Commun., 28:1 (2018), 39–40
Linking options:
https://www.mathnet.ru/eng/mendc1656
https://www.mathnet.ru/eng/mendc/v28/i1/p39
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