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Mendeleev Communications, 2018, Volume 28, Issue 3, Pages 275–277
DOI: https://doi.org/10.1016/j.mencom.2018.05.015
(Mi mendc1736)
 

This article is cited in 16 scientific papers (total in 16 papers)

Communications

Photophysical and photochemical properties of non-peripheral butoxy-substituted phthalocyanines with absorption in NIR range

E. A. Safonovaa, I. N. Meshkova, M. A. Polovkovaa, M. V. Volostnykha, A. Yu. Tsivadzeab, Yu. G. Gorbunovaab

a A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Abstract: The optical properties of non-peripheral octabutoxyphthalocyanine (PcH2) and the corresponding complexes PcM (M =MgII, ZnII, GaIII, InIII) in DMSO solutions were examined. Singlet oxygen generation quantum yields increase in the sequence PcH2 < PcMg < PcInCl < PcGaCl < PcZn and vary from 4 up to 36%; protonation of PcM quenches both fluorescence and singlet oxygen generation. The photocatalytic activity of PcGaCl in the photooxidation of 1,5-dihydroxynaphthalene was revealed.
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Document Type: Article
Language: English


Citation: E. A. Safonova, I. N. Meshkov, M. A. Polovkova, M. V. Volostnykh, A. Yu. Tsivadze, Yu. G. Gorbunova, “Photophysical and photochemical properties of non-peripheral butoxy-substituted phthalocyanines with absorption in NIR range”, Mendeleev Commun., 28:3 (2018), 275–277
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  • https://www.mathnet.ru/eng/mendc/v28/i3/p275
  • This publication is cited in the following 16 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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