D. V. Davydov, V. V. Chernyshev, V. B. Rybakov, Yu. F. Oprunenko, I. P. Beletskaya, “Regioselective N1- or N2-modification of benzotriazoles with iodonium salts in the presence of copper compounds”, Mendeleev Commun., 28:3 (2018), 287

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Mendeleev Communications, 2018, Volume 28, Issue 3, Pages 287–289
DOI: https://doi.org/10.1016/j.mencom.2018.05.019 (Mi mendc1740)

This article is cited in 6 scientific papers (total in 6 papers)

Communications

Regioselective N¹- or N²-modification of benzotriazoles with iodonium salts in the presence of copper compounds

D. V. Davydov, V. V. Chernyshev, V. B. Rybakov, Yu. F. Oprunenko, I. P. Beletskaya

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Full-text PDF (444 kB) Citations (6)

DOI: https://doi.org/10.1016/j.mencom.2018.05.019

Graphic abstract: Regioselective N<sup>1</sup>- or N<sup>2</sup>-modification of benzotriazoles with iodonium salts in the presence of copper compounds

Abstract: Modification of benzotriazoles with iodonium salts [diphenyl- and (E)-styrylphenyliodonium tosylates] occurs at the N¹-position in the presence of K₂CO₃ as a base and CuI as a catalyst in CH₂Cl₂, whereas in the presence of stoichiometric amount of [Cu₂(TMEDA)₂(OH)₂]Cl₂ complex regioselective N²-modification proceeds. Two new Cu^I complexes based on benzotriazoles were synthesized and their crystal structures were determined by X-ray powder diffraction analysis.

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Document Type: Article

Language: English

Citation: D. V. Davydov, V. V. Chernyshev, V. B. Rybakov, Yu. F. Oprunenko, I. P. Beletskaya, “Regioselective N¹- or N²-modification of benzotriazoles with iodonium salts in the presence of copper compounds”, Mendeleev Commun., 28:3 (2018), 287–289

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https://www.mathnet.ru/eng/mendc/v28/i3/p287

This publication is cited in the following 6 articles:

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