S. S. Kuvshinova, A. F. Smol'yakov, D. V. Vorobyeva, S. N. Osipov, D. A. Loginov, “CF3-Carbenoid functionalization of N-(pyrimidin-2-yl)indole catalyzed by cobalt complexes: Ligand control of selectivity”, Mendeleev Commun., 28:4 (2018), 359

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Mendeleev Communications, 2018, Volume 28, Issue 4, Pages 359–361
DOI: https://doi.org/10.1016/j.mencom.2018.07.005 (Mi mendc1765)

This article is cited in 13 scientific papers (total in 13 papers)

Communications

CF3-Carbenoid functionalization of N-(pyrimidin-2-yl)indole catalyzed by cobalt complexes: Ligand control of selectivity

S. S. Kuvshinova^a, A. F. Smol'yakov^ab, D. V. Vorobyeva^a, S. N. Osipov^a, D. A. Loginov^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation

Full-text PDF (427 kB) Citations (13)

DOI: https://doi.org/10.1016/j.mencom.2018.07.005

Graphic abstract: CF3-Carbenoid functionalization of N-(pyrimidin-2-yl)indole catalyzed by cobalt complexes: Ligand control of selectivity

Abstract: The carbonyl cobalt complex Cp*Co(CO)I₂ catalyzes carbenoid Co alkylation of N-(pyrimidin-2-yl)indole with methyl 3,3,3-trifluoro-2-diazopropionate regioselectively giving 2-substituted indole, while the N,N’-ligated cations [CpCo(L)I]⁺ (L=bipy, phen) provide 3-substitution exclusively. The structure of [CpCo(phen)I]PF₆ was investigated by X-ray diffraction.

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Document Type: Article

Language: English

Citation: S. S. Kuvshinova, A. F. Smol'yakov, D. V. Vorobyeva, S. N. Osipov, D. A. Loginov, “CF3-Carbenoid functionalization of N-(pyrimidin-2-yl)indole catalyzed by cobalt complexes: Ligand control of selectivity”, Mendeleev Commun., 28:4 (2018), 359–361

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https://www.mathnet.ru/eng/mendc/v28/i4/p359

This publication is cited in the following 13 articles:

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