Abstract:
Three phosphines bearing halodifluoromethyl group were obtained starting from chlorodiphenylphosphine. Silicon reagents Me3SiCF2X (X=Cl, Br) were used to install chloroor bromodifluoromethyl group to the phosphorus atom. Iododifluoromethyl-substituted phosphine was prepared by bromine/iodine exchange.
Bibliographic databases:
Document Type:
Article
Language: English
Citation:
R. O. Iakovenko, A. D. Dilman, “Synthesis of halodifluoromethyl-substituted phosphines”, Mendeleev Commun., 28:4 (2018), 396–397
Linking options:
https://www.mathnet.ru/eng/mendc1778
https://www.mathnet.ru/eng/mendc/v28/i4/p396
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