L. A. Hayriyan, A. F. Mkrtchyan, M. A. Moskalenko, V. I. Maleev, Z. T. Gugkaeva, M. M. Ilyin, K. K. Babievsky, P. V. Dorovatovskii, V. N. Khrustalev, A. S. Peregudov, Yu. N. Belokon, “Nickel-coordinated chiral enols and Michael addition intermediate stabilized by the Ni–C bond”, Mendeleev Commun., 28:5 (2018), 464

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Mendeleev Communications, 2018, Volume 28, Issue 5, Pages 464–466
DOI: https://doi.org/10.1016/j.mencom.2018.09.003 (Mi mendc1801)

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Nickel-coordinated chiral enols and Michael addition intermediate stabilized by the Ni–C bond

L. A. Hayriyan^a, A. F. Mkrtchyan^a, M. A. Moskalenko^b, V. I. Maleev^b, Z. T. Gugkaeva^b, M. M. Ilyin^b, K. K. Babievsky^b, P. V. Dorovatovskii^c, V. N. Khrustalev^cd, A. S. Peregudov^b, Yu. N. Belokon^b

^a Scientific and Production Center ‘Armbiotechnology’ of National Academy of Sciences of Republic Armenia, Yerevan, Armenia
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c National Research Centre 'Kurchatov Institute', Moscow, Russian Federation
^d Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation

Full-text PDF (501 kB) Citations (1) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2018.09.003

Graphic abstract: Nickel-coordinated chiral enols and Michael addition intermediate stabilized by the Ni–C bond

Abstract: A representative within a new class of chiral enol Ni^II complexes derived from a Schiff base of aminoacetone and (S)-2-N-(N-benzylprolinoylamino)benzophenone was prepared, and its performance in nucleophilic addition was estimated. The complex was inert towards aldehydes and activated C=C bonds but reacted with carboxylic anhydrides and di-tert-butyl acetylenedicarboxylate. An unusual Michael addition intermediate stabilized by the Ni–C bond was discovered in the latter reaction.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.4 Mb)

Citation: L. A. Hayriyan, A. F. Mkrtchyan, M. A. Moskalenko, V. I. Maleev, Z. T. Gugkaeva, M. M. Ilyin, K. K. Babievsky, P. V. Dorovatovskii, V. N. Khrustalev, A. S. Peregudov, Yu. N. Belokon, “Nickel-coordinated chiral enols and Michael addition intermediate stabilized by the Ni–C bond”, Mendeleev Commun., 28:5 (2018), 464–466

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https://www.mathnet.ru/eng/mendc/v28/i5/p464

This publication is cited in the following 1 articles:

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