Abstract:
Aminomethylation of thiophosphorylated calix[4]resorcinol with formaldehyde and secondary amines affords the novel Mannich base derivatives possessing better solubility. The nickel complex of morpholinomethyl derivative exhibits a good catalytic activity in hydrogen evolution decreasing potential of direct acid reduction on glassy carbon electrode to 1.3V.
Citation:
I. R. Mironova (Knyazeva), V. I. Matveeva, V. V. Khrizanforova, Yu. H. Budnikova, A. R. Burilov, “Novel thiophosphorylated calix[4]resorcinol Mannich bases and their electrochemical behavior in hydrogen evolution reaction”, Mendeleev Commun., 28:5 (2018), 515–517
Linking options:
https://www.mathnet.ru/eng/mendc1820
https://www.mathnet.ru/eng/mendc/v28/i5/p515
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