M. V. Andreev, I. A. Akishkina, V. S. Bogdanov, A. F. Smol'yakov, V. V. Burlakov, “Cyclization of adiponitrile in the reaction with diphenylzirconocene”, Mendeleev Commun., 34:4 (2024), 550

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Mendeleev Communications, 2024, Volume 34, Issue 4, Pages 550–551
DOI: https://doi.org/10.1016/j.mencom.2024.06.026 (Mi mendc183)

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Cyclization of adiponitrile in the reaction with diphenylzirconocene

M. V. Andreev^a, I. A. Akishkina^ab, V. S. Bogdanov^a, A. F. Smol'yakov^ac, V. V. Burlakov^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^c G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation

Full-text PDF (232 kB) Citations (1) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2024.06.026

Graphic abstract: Cyclization of adiponitrile in the reaction with diphenylzirconocene

Abstract: Intramolecular cyclization of adiponitrile with the formation of an amidinate functional group in zirconium coordination sphere was found. The obtained complex can be protolyzed with HCl in dioxane to afford a new representative of amidines, namely, 7-phenyl-1,3,4,5-tetrahydro-2H-azepin-2- imine in hydrochloride form.

Keywords: zirconium, adiponitrile, cyclization, amidines, amidinate, azepines.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(669.8 Kb)

Citation: M. V. Andreev, I. A. Akishkina, V. S. Bogdanov, A. F. Smol'yakov, V. V. Burlakov, “Cyclization of adiponitrile in the reaction with diphenylzirconocene”, Mendeleev Commun., 34:4 (2024), 550–551

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https://www.mathnet.ru/eng/mendc183

https://www.mathnet.ru/eng/mendc/v34/i4/p550

This publication is cited in the following 1 articles:

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