Abstract:
The in situ DRIFT-CO and XPS data demonstrated that the mild oxidation of PdIn intermetallic nanoparticles results in the partial oxidation of an In component and the trans-formation of isolated Pd1 sites to Pdn multiatomic ones thus enhancing PdIn activity in the liquid-phase hydrogenation of diphenylacetylene without sacrificing the alkene selectivity.
Citation:
I. S. Mashkovsky, N. S. Smirnova, P. V. Markov, G. N. Baeva, G. O. Bragina, A. V. Bukhtiyarov, I. P. Prosvirin, A. Yu. Stakheev, “Tuning the surface structure and catalytic performance of PdIn/Al2O3 in selective liquid-phase hydrogenation by mild oxidative-reductive treatments”, Mendeleev Commun., 28:6 (2018), 603–605
Linking options:
https://www.mathnet.ru/eng/mendc1850
https://www.mathnet.ru/eng/mendc/v28/i6/p603
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