Yu. M. Volkova, A. Yu. Makarov, S. B. Zikirin, A. M. Genaev, I. Yu. Bagryanskaya, A. V. Zibarev, “3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals”, Mendeleev Commun., 27:1 (2017), 19

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Mendeleev Communications, 2017, Volume 27, Issue 1, Pages 19–22
DOI: https://doi.org/10.1016/j.mencom.2017.01.005 (Mi mendc1882)

This article is cited in 17 scientific papers (total in 17 papers)

Communications

3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals

Yu. M. Volkova^a, A. Yu. Makarov^a, S. B. Zikirin^bc, A. M. Genaev^a, I. Yu. Bagryanskaya^ad, A. V. Zibarev^ae

^a N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^c Department of Physics, Novosibirsk State University, Novosibirsk, Russian Federation
^d Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation
^e Department of Chemistry, National Research Tomsk State University, Tomsk, Russian Federation

Full-text PDF (494 kB) Citations (17) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2017.01.005

Graphic abstract: 3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals

Abstract: The archetypal 3,1,2,4-benzothiaselenadiazine, its 5- and 8-Me₃Si derivatives and related dithiadiazine and trithiadiazepine were synthesized from 2-Me₃SiC₆H₄N=S=NSiMe₃ by the action of SeCl₂, SeCl₄, SCl₂, and S₂Cl₂ and converted into persistent 2,1,3-benzothiaselenazolyl and 1,2,3-benzodithiazolyl radicals characterized by EPR spectroscopy and DFT calculations.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(434.1 Kb)

Citation: Yu. M. Volkova, A. Yu. Makarov, S. B. Zikirin, A. M. Genaev, I. Yu. Bagryanskaya, A. V. Zibarev, “3,1,2,4-Benzothiaselenadiazine and related heterocycles: synthesis and transformation into Herz-type radicals”, Mendeleev Commun., 27:1 (2017), 19–22

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https://www.mathnet.ru/eng/mendc/v27/i1/p19

This publication is cited in the following 17 articles:

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