Abstract:
A new one-pot synthesis of 3-R-1H-phospholane oxides (57–65% yield) was implemented by reaction of phosphorus tri- or pentahalides with 3-R-1-aluminacyclopentanes (in situ generated by Zr-catalyzed cycloalumination of alkenes). The products are readily P-vinylated by Cu-promoted reaction with alkynes.
Citation:
L. K. Dil'mukhametova, T. V. Tyumkina, V. A. D'yakonov, U. M. Dzhemilev, “Zirconium-catalyzed cycloalumination of alkenes in the one-pot synthesis of 3-substituted 1H-phospholane oxides”, Mendeleev Commun., 27:1 (2017), 23–25
Linking options:
https://www.mathnet.ru/eng/mendc1883
https://www.mathnet.ru/eng/mendc/v27/i1/p23
This publication is cited in the following 6 articles: