V. P. Zelenov, S. S. Bukalov, L. A. Leites, R. R. Aysin, A. N. Subbotin, M. I. Struchkova, I. V. Fedyanin, “Trifluoroacetyl nitrate”, Mendeleev Commun., 27:1 (2017), 31

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Mendeleev Communications, 2017, Volume 27, Issue 1, Pages 31–34
DOI: https://doi.org/10.1016/j.mencom.2017.01.009 (Mi mendc1886)

This article is cited in 13 scientific papers (total in 13 papers)

Communications

Trifluoroacetyl nitrate

V. P. Zelenov^a, S. S. Bukalov^b, L. A. Leites^b, R. R. Aysin^b, A. N. Subbotin^a, M. I. Struchkova^a, I. V. Fedyanin^b

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (309 kB) Citations (13) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2017.01.009

Graphic abstract: Trifluoroacetyl nitrate

Abstract: Individual trifluoroacetyl nitrate (TFAN) was synthesized by the reaction of N₂O₅ with trifluoroacetic anhydride (TFAA) and was characterized by ¹³C, ¹⁴N, ¹⁵N, and ¹⁹F NMR and Raman spectroscopy. In the gas phase TFAN partially decomposes into N₂O₅ and TFAA, and in solutions the equilibrium is shifted to TFAN. Mono nitration of [2.2]paracyclophane with TFAN proceeds in good yields.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.0 Mb)

Citation: V. P. Zelenov, S. S. Bukalov, L. A. Leites, R. R. Aysin, A. N. Subbotin, M. I. Struchkova, I. V. Fedyanin, “Trifluoroacetyl nitrate”, Mendeleev Commun., 27:1 (2017), 31–34

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https://www.mathnet.ru/eng/mendc/v27/i1/p31

This publication is cited in the following 13 articles:

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