Abstract:
Zirconocene obtained from 6,6-dimethylfulvene ‘dimer’, being activated subsequently with triisobutylaluminium and methylalumoxane, catalyzes transformation of α-olefins into a mixture of vinylidene oligomers with minimal losses to isomerization, which allows one to consider this catalyst perspective for the synthesis of branched hydrocarbons with uniform structure.
Citation:
I. E. Nifant'ev, A. A. Vinogradov, A. A. Vinogradov, S. I. Bezzubov, P. V. Ivchenko, “Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’”, Mendeleev Commun., 27:1 (2017), 35–37
Linking options:
https://www.mathnet.ru/eng/mendc1887
https://www.mathnet.ru/eng/mendc/v27/i1/p35
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