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Mendeleev Communications, 2017, Volume 27, Issue 1, Pages 35–37
DOI: https://doi.org/10.1016/j.mencom.2017.01.010
(Mi mendc1887)
 

This article is cited in 19 scientific papers (total in 19 papers)

Communications

Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’

I. E. Nifant'evab, A. A. Vinogradovb, A. A. Vinogradovb, S. I. Bezzubovc, P. V. Ivchenkoab

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Abstract: Zirconocene obtained from 6,6-dimethylfulvene ‘dimer’, being activated subsequently with triisobutylaluminium and methylalumoxane, catalyzes transformation of α-olefins into a mixture of vinylidene oligomers with minimal losses to isomerization, which allows one to consider this catalyst perspective for the synthesis of branched hydrocarbons with uniform structure.
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Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (430.3 Kb)


Citation: I. E. Nifant'ev, A. A. Vinogradov, A. A. Vinogradov, S. I. Bezzubov, P. V. Ivchenko, “Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’”, Mendeleev Commun., 27:1 (2017), 35–37
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  • https://www.mathnet.ru/eng/mendc/v27/i1/p35
  • This publication is cited in the following 19 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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