V. Yu. Kotov, A. B. Ilyukhin, A. A. Sadovnikov, K. P. Birin, N. P. Simonenko, H. T. Nguyen, A. Y. Baranchikov, S. A. Kozyukhin, “Bis(4-cyano-1-pyridino)pentane halobismuthates. Light-harvesting material with an optical band gap of 1.59 eV”, Mendeleev Commun., 27:3 (2017), 271

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Mendeleev Communications, 2017, Volume 27, Issue 3, Pages 271–273
DOI: https://doi.org/10.1016/j.mencom.2017.05.018 (Mi mendc1965)

This article is cited in 29 scientific papers (total in 29 papers)

Communications

Bis(4-cyano-1-pyridino)pentane halobismuthates. Light-harvesting material with an optical band gap of 1.59 eV

V. Yu. Kotov^ab, A. B. Ilyukhin^a, A. A. Sadovnikov^a, K. P. Birin^c, N. P. Simonenko^a, H. T. Nguyen^a, A. Y. Baranchikov^ad, S. A. Kozyukhin^a

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^c A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
^d Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Full-text PDF (467 kB) Citations (29) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2017.05.018

Graphic abstract: Bis(4-cyano-1-pyridino)pentane halobismuthates. Light-harvesting material with an optical band gap of 1.59 eV

Abstract: A new organic-inorganic hybrid material composed of 0-D bromobismuthate anions and bis(4-cyano-1-pyridino)pentane cations was synthesized and characterized. The replacement of Br with I resulted in a decrease in the optical band gap from 2.88 eV for (C₁₇H₁₈N₄)₂Bi₂Br₁₀ to 1.59 eV for (C₁₇H₁₈N₄)BiI₅. Thus, (C₁₇H₁₈N₄)BiI₅ can be proposed as a candidate material for solid state solar cells.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(976.0 Kb)

Citation: V. Yu. Kotov, A. B. Ilyukhin, A. A. Sadovnikov, K. P. Birin, N. P. Simonenko, H. T. Nguyen, A. Y. Baranchikov, S. A. Kozyukhin, “Bis(4-cyano-1-pyridino)pentane halobismuthates. Light-harvesting material with an optical band gap of 1.59 eV”, Mendeleev Commun., 27:3 (2017), 271–273

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This publication is cited in the following 29 articles:

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