Abstract:
A new GdIII complex with the tridentate chelating redox ligand 2,4,6,8-tetrakis(tert-butyl)-9-hydroxyphenoxazinone was synthesized and studied by X-ray crystallography, ESR spectroscopy and magnetic measurements. The rigid tricyclic framework of the ligands ensures the formation of a nine-coordinate environment of GdIII surrounded by three nitrogen and six oxygen atoms in the form of a tricapped trigonal prism.
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Document Type:
Article
Language: English
Citation:
E. P. Ivakhnenko, V. I. Simakov, P. A. Knyazev, G. V. Romanenko, A. S. Bogomyakov, V. I. Minkin, “Synthesis and structure of a tris-chelate GdIII complex with tridentate 2,4,6,8-tetrakis(tert-butyl)-9-hydroxyphenoxazinone ligands”, Mendeleev Commun., 26:1 (2016), 49–51
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https://www.mathnet.ru/eng/mendc2106
https://www.mathnet.ru/eng/mendc/v26/i1/p49
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