Abstract:
Prolonged treatment of menth-4-en-3-yl sulfides with H2O2 in acidic medium leads to saturated menthan-3-yl sulfones, the same products having been obtained from menth-4-en-3-yl sulfoxides in acidic medium in the absence of H2O2. The mechanism was evaluated by quantum chemical calculations.
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Document Type:
Article
Language: English
Citation:
G. Yu. Ishmuratov, V. S. Tukhvatshin, M. P. Yakovleva, I. V. Vakulin, R. R. Muslukhov, P. A. Pasko, R. F. Talipov, “Unexpected acidic transformation of allylic menthene sulfoxides into saturated sulfones”, Mendeleev Commun., 26:1 (2016), 81–82
Linking options:
https://www.mathnet.ru/eng/mendc2119
https://www.mathnet.ru/eng/mendc/v26/i1/p81
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