Abstract:
β-Diketones and β-oxo esters are thiocyanated with the NaSCN/(NH4)2 Ce(NO3)6 system or with pre-generated dirhodanogen. Malonates undergo thiocyanation only with the NaSCN/(NH4)2 Ce(NO3)6 system.
Citation:
A. O. Terent'ev, M. Yu. Sharipov, A. P. Glinuskin, I. B. Krylov, D. V. Gaidarenko, G. I. Nikishin, “Difference in α-thiocyanation of malonates, β-oxo esters and β-diketones with sodium thiocyanate and cerium(IV) ammonium nitrate”, Mendeleev Commun., 26:3 (2016), 226–227
Linking options:
https://www.mathnet.ru/eng/mendc2167
https://www.mathnet.ru/eng/mendc/v26/i3/p226
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