Abstract:
Selective thiocyanation (yield 70–90%) at the 3-position of pyrazolo[1,5-a]pyrimidines was performed with thiocyanogen electrochemically generated in situ from NH4SCN in MeCN on a Pt anode. For substrates with higher oxidation potential addition of Lewis acids was necessary.
Bibliographic databases:
Document Type:
Article
Language: English
Citation:
V. A. Kokorekin, R. R. Yaubasarova, S. V. Neverov, V. A. Petrosyan, “Reactivity of electrogenerated thiocyanogen in the thiocyanation of pyrazolo[1,5-a]pyrimidines”, Mendeleev Commun., 26:5 (2016), 413–414
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https://www.mathnet.ru/eng/mendc2231
https://www.mathnet.ru/eng/mendc/v26/i5/p413
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