Abstract:
The reactions of [(η5-indenyl)IrI2]η with CpTl or arenes in the presence of AgBF4 afford [(η5-indenyl)IrCp]+ or [(η5-indenyl)Ir(arene)]2+ cations (arene = benzene, mesitylene, durene or hexamethylbenzene); the structures of (η5-indenyl)-Ir(C2H4)2 and [(η5-indenyl)IrCp]PF6 were characterized by X-ray diffraction analysis.
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Document Type:
Article
Language: English
Citation:
A. A. Chamkin, A. M. Finogenova, Yu. V. Nelyubina, J. N. Laskova, A. R. Kudinov, D. A. Loginov, “Iodide [(η5-indenyl)IrI2]n: an effective precursor to (indenyl)iridium sandwich complexes”, Mendeleev Commun., 26:6 (2016), 491–493
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https://www.mathnet.ru/eng/mendc2256
https://www.mathnet.ru/eng/mendc/v26/i6/p491
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