P. V. Markov, G. O. Bragina, A. V. Rassolov, G. N. Baeva, I. S. Mashkovsky, V. Yu. Murzin, Ya. V. Zubavichus, A. Yu. Stakheev, “Pd–Cu catalyst prepared from heterobimetallic PdCu2(OAc)6: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond”, Mendeleev Commun., 26:6 (2016), 502

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Mendeleev Communications, 2016, Volume 26, Issue 6, Pages 502–504
DOI: https://doi.org/10.1016/j.mencom.2016.11.014 (Mi mendc2260)

This article is cited in 28 scientific papers (total in 28 papers)

Communications

Pd–Cu catalyst prepared from heterobimetallic PdCu₂(OAc)₆: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond

P. V. Markov^a, G. O. Bragina^a, A. V. Rassolov^a, G. N. Baeva^a, I. S. Mashkovsky^a, V. Yu. Murzin^b, Ya. V. Zubavichus^b, A. Yu. Stakheev^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b National Research Centre 'Kurchatov Institute', Moscow, Russian Federation

Full-text PDF (617 kB) Citations (28) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2016.11.014

Graphic abstract: Pd–Cu catalyst prepared from heterobimetallic PdCu<sub>2</sub>(OAc)<sub>6</sub>: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond

Abstract: The formation of a PdCu alloy with an fcc structure in 1% Pd–1.2% Cu₂ /Al₂O₃ (as evidenced by XRD and EXAFS data) significantly improves catalyst selectivity in the semihydrogenation of internal and terminal alkynes, which makes 1% Pd–1.2% Cu₂ /Al₂O₃ a promising alternative to the commercial Lindlar catalyst.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(237.0 Kb)

Citation: P. V. Markov, G. O. Bragina, A. V. Rassolov, G. N. Baeva, I. S. Mashkovsky, V. Yu. Murzin, Ya. V. Zubavichus, A. Yu. Stakheev, “Pd–Cu catalyst prepared from heterobimetallic PdCu₂(OAc)₆: an XRD-EXAFS study and activity/selectivity in the liquid-phase hydrogenation of a C≡C bond”, Mendeleev Commun., 26:6 (2016), 502–504

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https://www.mathnet.ru/eng/mendc/v26/i6/p502

This publication is cited in the following 28 articles:

Citing articles in Google Scholar: Russian citations, English citations
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