Abstract:
Reduction of aldehyde group in 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde leads to methoxymethyl (NaBH4, MeOH) or methyl (Zn, MeOH) analogues, which were further oxidized into the corresponding o-benzoquinones. Their photostability in benzene increases substantially on replacement of the 6-positioned Me substituent with the CH2OMe group.
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Document Type:
Article
Language: English
Citation:
M. V. Arsenyev, E. V. Baranov, M. P. Shurygina, S. A. Chesnokov, G. A. Abakumov, “New sterically-hindered catechols/o-benzoquinones. Reduction of 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde”, Mendeleev Commun., 26:6 (2016), 552–554
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https://www.mathnet.ru/eng/mendc2278
https://www.mathnet.ru/eng/mendc/v26/i6/p552
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