T. V. Sviridova, L. Yu. Sadovskaya, O. V. Matrosova, M. V. Vishnetskaya, A. I. Kokorin, D. V. Sviridov, “Catalytic activity of MoO3:V2O5 mixed oxides towards oxidation reactions: the nature of catalytic centers”, Mendeleev Commun., 34:5 (2024), 715

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Mendeleev Communications, 2024, Volume 34, Issue 5, Pages 715–717
DOI: https://doi.org/10.1016/j.mencom.2024.09.029 (Mi mendc230)

This article is cited in 2 scientific papers (total in 2 papers)

Communications

Catalytic activity of MoO₃:V₂O₅ mixed oxides towards oxidation reactions: the nature of catalytic centers

T. V. Sviridova^a, L. Yu. Sadovskaya^a, O. V. Matrosova^b, M. V. Vishnetskaya^b, A. I. Kokorin^cde, D. V. Sviridov^a

^a Department of Chemistry, Belarusian State University, Minsk, Belarus
^b National University of Oil and Gas ‘Gubkin University’, Moscow, Russian Federation
^c N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^d G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation
^e Infochemistry Scientific Center, ITMO University, St. Petersburg, Russian Federation

Full-text PDF (373 kB) Citations (2) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2024.09.029

Graphic abstract: Catalytic activity of MoO<sub>3</sub>:V<sub>2</sub>O<sub>5</sub> mixed oxides towards oxidation reactions: the nature of catalytic centers

Abstract: Singlet oxygen emission and peroxide generation at the surface of molybdenum–vanadium oxides evidenced that the catalytic activity of a MoO₃:V₂O₅ mixed oxide at 70–175 °C was governed by the formation of peroxo groups in the interaction of molecular oxygen with adjacent V^iv surface centers; the thermolysis of these groups yielded singlet oxygen capable of oxidizing selectively alcohols to aldehydes.

Keywords: molybdenum–vanadium mixed oxides, singlet oxygen, catalysis, oxidation, peroxo groups, clusterization of redox centers.

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Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(879.2 Kb)

Citation: T. V. Sviridova, L. Yu. Sadovskaya, O. V. Matrosova, M. V. Vishnetskaya, A. I. Kokorin, D. V. Sviridov, “Catalytic activity of MoO₃:V₂O₅ mixed oxides towards oxidation reactions: the nature of catalytic centers”, Mendeleev Commun., 34:5 (2024), 715–717

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https://www.mathnet.ru/eng/mendc230

https://www.mathnet.ru/eng/mendc/v34/i5/p715

This publication is cited in the following 2 articles:

Citing articles in Google Scholar: Russian citations, English citations
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