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Mendeleev Communications, 2015, Volume 25, Issue 2, Pages 109–110
DOI: https://doi.org/10.1016/j.mencom.2015.03.009 (Mi mendc2315) 		 
This article is cited in 2 scientific papers (total in 2 papers)

Communications

Versatile reactivity of amines towards the ruthenocenylmethylium cation [Cp*Ru(C5Me4CH2)]+

D. V. Muratov, A. S. Romanov, A. R. Kudinov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Full-text PDF (629 kB) Citations (2) Supplementary materials
DOI: https://doi.org/10.1016/j.mencom.2015.03.009
Abstract: The cationic complex [Cp*Ru(C5Me4CH2)]+ reacts with Et3N primarily giving the ammonium salt [Cp*Ru(C5Me4CH2NEt3)]+. The prolonged standing of the reaction mixture results in the formation of the ether Cp*Ru(C5Me4CH2OCH2C5Me4)RuCp*. The reaction of [Cp*Ru(C5Me4CH2)]+ with PhNEt2 leads to the electrophilic aromatic substitution product [Cp*Ru(C5Me4CH2C6H4NHEt2)]+.
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Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (373.7 Kb)


Citation: D. V. Muratov, A. S. Romanov, A. R. Kudinov, “Versatile reactivity of amines towards the ruthenocenylmethylium cation [Cp*Ru(C5Me4CH2)]+”, Mendeleev Commun., 25:2 (2015), 109–110
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  • https://www.mathnet.ru/eng/mendc/v25/i2/p109
    • This publication is cited in the following 2 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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