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Mendeleev Communications, 2024, Volume 34, Issue 5, Pages 732–733
DOI: https://doi.org/10.1016/j.mencom.2024.09.034
(Mi mendc235)
 

This article is cited in 2 scientific papers (total in 2 papers)

Communications

N-Vinylation of lactams with calcium carbide water system

Yu. V. Gyrdymova, S. M. Zarubina, K. S. Rodygin

Institute of Chemistry, St. Petersburg State University, St. Petersburg, Russian Federation
Abstract: Direct N-vinylation of lactams with calcium carbide water system was performed under super-basic conditions. The vinylation occurred exclusively at NH group leaving C=O function intact to afford cyclic N-vinyl amides in yields up to 97%. The obtained products are prospective monomers for the preparation of synthetic peptides.
Keywords: lactams, vinylation, calcium carbide, vinyl carboxamides, acetylene, synthetic peptides.
Bibliographic databases:
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (2.1 Mb)


Citation: Yu. V. Gyrdymova, S. M. Zarubina, K. S. Rodygin, “N-Vinylation of lactams with calcium carbide water system”, Mendeleev Commun., 34:5 (2024), 732–733
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  • https://www.mathnet.ru/eng/mendc/v34/i5/p732
  • This publication is cited in the following 2 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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