Abstract:
A new polyherdal nickel siloxane was synthesized by the hydrolysis of triethoxy(4-vinylbenzyl)silane in the presence of NaOH and the subsequent interaction with [Ni(NH3)6]Cl2. The nickel siloxane has a dimeric structure that consists of two polyhedral sandwiched pentanuclear nickel siloxane units linked by very strong O–H···O bonds into infinite chains in a crystal.
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Document Type:
Article
Language: English
Citation:
A. A. Korlyukov, M. A. Eskova, I. M. Tkachenko, Yu. N. Kononevich, O. I. Shchegolikhina, A. M. Muzafarov, “Heteroligand nickel siloxane with 4-vinylbenzyl substituents”, Mendeleev Commun., 25:3 (2015), 226–228
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https://www.mathnet.ru/eng/mendc2360
https://www.mathnet.ru/eng/mendc/v25/i3/p226
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