S. F. Vasilevskii, M. P. Davydova, V. I. Mamatyuk, N. V. Pleshkova, D. S. Fadeev, I. V. Alabugin, “Reaction of α,β-alkynylketones with β-amino alcohols: pseudoephedrine- assisted cleavage of triple bond via formal internal redox process”, Mendeleev Commun., 25:5 (2015), 377

Mendeleev Communications

RUS ENG

JOURNALS PEOPLE ORGANISATIONS CONFERENCES SEMINARS VIDEO LIBRARY PACKAGE AMSBIB

JavaScript is disabled in your browser. Please switch it on to enable full functionality of the website

	General information
	Latest issue
	Archive

	Search papers
	Search references

	RSS
	Latest issue
	Current issues
	Archive issues
	What is RSS

Mendeleev Commun.:
Year:
Volume:
Issue:
Page:
	Find

Personal entry:
Login:
Password:
	Save password
	Enter
	Forgotten password?
	Register

Mendeleev Communications, 2015, Volume 25, Issue 5, Pages 377–379
DOI: https://doi.org/10.1016/j.mencom.2015.09.021 (Mi mendc2415)

This article is cited in 9 scientific papers (total in 9 papers)

Communications

Reaction of α,β-alkynylketones with β-amino alcohols: pseudoephedrine- assisted cleavage of triple bond via formal internal redox process

S. F. Vasilevskii^ab, M. P. Davydova^a, V. I. Mamatyuk^bc, N. V. Pleshkova^c, D. S. Fadeev^c, I. V. Alabugin^d

^a V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b Novosibirsk State University, Novosibirsk, Russian Federation
^c N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^d Department of Chemistry, Florida State University, Tallahassee, USA

Full-text PDF (264 kB) Citations (9) Supplementary materials

DOI: https://doi.org/10.1016/j.mencom.2015.09.021

Graphic abstract: Reaction of α,β-alkynylketones with β-amino alcohols: pseudoephedrine- assisted cleavage of triple bond <i>via</i> formal internal redox process

Abstract: Reaction of 3-aryl-1-(3,4,5-trimethoxyphenyl)prop-2-yn-1-ones with (+)-pseudoephedrine leads to products of alkyne moiety cleavage, namely, 1-(3,4,5-trimethoxyphenyl)ethanone and N-(1-hydroxy-1-phenylprop-2-yl)-N-methylbenzamides. In the course of the process one of alkyne carbons undergoes a formal reduction to a Me group, whereas the other one is oxidized to a C(O)NRR’ moiety.

Bibliographic databases:

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(346.3 Kb)

Citation: S. F. Vasilevskii, M. P. Davydova, V. I. Mamatyuk, N. V. Pleshkova, D. S. Fadeev, I. V. Alabugin, “Reaction of α,β-alkynylketones with β-amino alcohols: pseudoephedrine- assisted cleavage of triple bond via formal internal redox process”, Mendeleev Commun., 25:5 (2015), 377–379

Linking options:

https://www.mathnet.ru/eng/mendc2415

https://www.mathnet.ru/eng/mendc/v25/i5/p377

This publication is cited in the following 9 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

Registration to the website

Logotypes