Abstract:α,α-Bis[bis-3,5-(trifluoromethyl)phenyl]prolinol silyl ether anchored onto polystyrene was synthesized and tested in asymmetric α-amination of aldehydes. The catalytic activity and enantioselectivity of the immobilized catalyst persist for 3 cycles.
Citation:
A. A. Guryev, M. V. Anokhin, A. D. Averin, I. P. Beletskaya, “Polymer-immobilized α,α-bis[bis-3,5-(trifluoromethyl)phenyl]prolinol silyl ether: synthesis and application in the asymmetric α-amination of aldehydes”, Mendeleev Commun., 25:6 (2015), 410–411
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https://www.mathnet.ru/eng/mendc2426
https://www.mathnet.ru/eng/mendc/v25/i6/p410
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