Abstract:N-Allyl-N-methylanilines react with methyl diazoacetate or diazoacetone in the presence of Y, Sc or Sm triflates to give the corresponding methyl N-(2-allylaryl)-N-methylglycinates or 2-allyl-N-methyl-N-(2-oxopropyl)aniline. The formation of these compounds involves the aza-Claisen rearrangement.
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Article
Language: English
Citation:
A. G. Badamshin, L. V. Spirikhin, R. F. Salikov, V. A. Dokichev, Yu. V. Tomilov, “Lewis acid-catalyzed reactions of N-allylanilines with diazo compounds involving aza-Claisen rearrangement”, Mendeleev Commun., 25:6 (2015), 438–439
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https://www.mathnet.ru/eng/mendc2437
https://www.mathnet.ru/eng/mendc/v25/i6/p438
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