Abstract:
SnCl4-promoted [4 + 2] cycloaddition of β-nitrostyrenes to 4-methylidene-1,3-dioxolane provides stereoselective synthesis of spirocyclic nitronates. 2-Nitrovinyl benzoate under the same conditions produces δ-substituted nitrodiene as a single E,E-isomer.
Citation:
A. A. Mikhaylov, P. A. Zhmurov, A. S. Naumova, Yu. A. Khoroshutina, A. Yu. Sukhorukov, S. L. Ioffe, “Stereoselective synthesis of spirocyclic nitronates by SnCl4-promoted reaction of nitroalkenes with C-2 substituted 4-methylidene-1,3-dioxolane”, Mendeleev Commun., 25:6 (2015), 449–451
Linking options:
https://www.mathnet.ru/eng/mendc2441
https://www.mathnet.ru/eng/mendc/v25/i6/p449
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